| 학회 |
한국고분자학회 |
| 학술대회 |
2005년 가을 (10/13 ~ 10/14, 제주 ICC) |
| 권호 |
30권 2호 |
| 발표분야 |
자기조립형 기능성재료 |
| 제목 |
Synthesis of Novel triblock Copolymers of Poly(methyl methacrylate)-b-Polypentafluorostyrene-b-Poly(methyl methacrylate) by Atom Transfer Radical Polymerization |
| 초록 |
Novel triblock copolymers of poly(methyl methacrylate)-b-polypentafluorostyrene-b-poly(methyl methacrylate) (PMMA-b-PPFS-b-PMMA) by ATRP technique. The atom transfer radical polymerization (ATRP) of pentafluorostyrene (PFS) and methyl methacrylate (MMA) was successfully performed at ambient temperature. Using a bromine terminated poly(pentafluorostyrene) macroinitiator, ATRP was performed at 75℃ using a catalytic complex (CuBr/PMDETA) in fluorobenzene. Evidences of block copolymerization were provided by GPC, 1H-NMR, thermal analysis and small angle X-ray scattering (SAXS). |
| 저자 |
고윤수, 권용구
|
| 소속 |
인하대 |
| 키워드 |
ATRP; atom transfer radical polymerization; self assembly; optical wave guide
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| E-Mail |
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