화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 고분자가공/복합재료
제목 Interfacial activation by N2 plasma-assisted mechanochemical reaction in nonpolar polymer
초록 Dispersion of nano-fillers is key issue in polymer nanocomposites. A number of researchers study the affinity between the nano-fillers and the polymer in order to modify the dispersion of the nano-fillers. Recent works have shown that the high shear forces are able to trigger bond-scission reaction and bond-activation, which have been called mechanochemical reaction. At this point, we found that there could be a meaningful change when shear force and plasma treatment were coupled in treating nonpolar polymer. Although there is no reactive functional group, a nonpolar polymer was found to be highly reactive temporarily under N2 plasma-assisted shear force, resulting in formidable chemical bondings between incompatible inorganic and organic interfaces.
저자 김민성1, 방준하2, 이상수2
소속 1한국과학기술(연), 2고려대
키워드 polymer composite; mechanochemistry; plasma; polypropylene; graphite nanoplatelet;
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