| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 봄 (04/23 ~ 04/25, 제주ICC) |
| 권호 |
14권 1호, p.1250 |
| 발표분야 |
재료 |
| 제목 |
Charicteristics of electrospun Poly(acrylonitrile)/SiO2 composite polymer electrolyte membrane |
| 초록 |
Poly(acrylonitrile) (PAN) is considered as a good polymer electrolyte membrane in rechargeable battery owning to mechanical property and chemical stability. However, PAN is limited about electrochemical performance due to the restriction of morphology. This work is focused on the enhancement of electrochemical performance by inducing microporous morphology using electrospinning technique and SiO2 as inorganic filler. Microporous poly(acrylonitrile)/SiO2 composite polymer electrolyte membrane was prepared by an electrospinning technique. The microporous morphology of PAN makes ion mobility much free, and silica keeps hold-up of liquid electrolyte easier. This leaded to much higher ionic conductivity. The morphology of the fiber web was analyzed by scanning electron microscopy(SEM) and the thermal stability was also analyzed by thermo gravimetric analysis(TGA), differential scanning calorimeter(DSC). The electrochemical performance of polymer electrolytes membrane were carried out using assembled Li-ion Polymer cell fabricated LiCoO2 as cathode and graphite as anode. |
| 저자 |
주동혁1, 정홍련2, 이완진1
|
| 소속 |
1전남대, 2Alan Mcdiarmid 에너지 (연) |
| 키워드 |
electrospinning; gel electrolyte; lithium ion battery
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| E-Mail |
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| 원문파일 |
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