| 초록 |
Ionic liquid (IL) of 1,1,3,3-tetramethylguanidinum trifluoroacetate, which was synthesized by the reaction between 1,1,3,3-tetramethylguanidine and trifluoroacetic acid, was used as a catalyst of the reaction between carbon dioxide and glycidyl methacrylate (GMA). Absorption rate of carbon dioxide into GMA solutions containing IL, which was measured in a semi-batch stirred tank with a plane gas-liquid interface at 101.3 kPa, was used to obtain the reaction kinetics from analysis of the mass transfer mechanism accompanied by the elementary reactions based on the film theory. |
