| 학회 | 한국화학공학회 |
| 학술대회 | 2011년 가을 (10/26 ~ 10/28, 송도컨벤시아) |
| 권호 | 17권 2호, p.1776 |
| 발표분야 | 이동현상 |
| 제목 | A study on computationalimplementation of cyclic voltammetry applying semi-infinite diffusion model |
| 초록 | The ionic transport phenomena near the electrode have been analyzed, herein the computational program to implement the electrical signal of cyclic voltammetry has been written by using MATLAB.For the ionic mass-transfer system, the governing equation and its boundary conditions are confined to the semi-infinite diffusion model and the reversible reaction at the electrode.In order to obtain the numerical solutions of cyclic voltammetry,the explicit finite difference method was applied.Experimental data for the cyclic voltammetry of10mM K3Fe(CN)6 and 0.1M KCl system upon the ITO glass electrode were compared with the numerical ones.Present program explains the experimental results reasonably well, in which they approached the simulated ones more closely with deceasing the scan rate.Furthermore,othereffects such as electrode area, electrochemical reaction constants and transfering coefficientswere discussed quantitatively in cyclic voltametic system. This work was supported by the NANO-Star center under the CRADA of AFIT-UT-KWU. |
| 저자 | 조하나, 김태용, 윤도영 |
| 소속 | 광운대 |
| 키워드 | Electrochemistry; MATLAB |
| 원문파일 | 초록 보기 |
