| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
The Performance of Nafion/Inorganic Nanocomposite IPMC Actuators Containing Silica, Layered Silicate, and Amphiphilic Organic Molecule |
| 초록 |
Nafion nanocomposite membranes were prepared using fumed silica, MMT, and an amphiphilic organic molecule (camphor-10-sulfonic acid(β); CSA). An organosilane (3-MPTMS) was grafted on the surface of silica and MMT, and the thiol groups on the fillers were sulfonated to endow them with additional metal ions. The modification of fillers and the incorporation of the fillers in Nafion matrix considerably altered the internal morphologies of hydrophilic ion-rich and hydrophobic fluorocarbon regions, followed by the change in thermal and mechanical properties, and mass transport kinetics. The actuation performance in terms of displacement and generated force was the best for IPMCs based on the Nafion/sulfonated MMT nanocomposite membrane among all samples prepared, although the proton conductivity of the Nafion/CSA membrane registered 0.123 S/cm in maximum superior to those of the pristine Nafion membrane (0.085 S/cm) and the others (0.0800.090 S/cm). |
| 저자 |
이장우1, 김지혜1, 이재열2, 유영태1
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| 소속 |
1건국대, 2국방나노응용 특화연구센터 / 국방과학(연) |
| 키워드 |
Ionic polymer-metal composite; Actuators; Silica; Montmorillonite; Camphorsulfonic acid; Nafion
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| E-Mail |
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