화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2021년 봄 (04/21 ~ 04/23, 부산 BEXCO)
권호 27권 1호, p.999
발표분야 촉매 및 반응공학
제목 Ordered Mesoporous 3D Graphene-Like Carbon Frameworks with Tubular Structure for Efficient Alkaline Hydrogen Evolution Reaction
초록 Ordered mesoporous carbons (OMCs) have been exploited in a wide range of industrial fields such as energy conversion and storage, catalysis, and gas adsorption. However, the previously reported OMCs showed trade-off relation between surface area and electrical conductivity. In this work, we synthesize ordered mesoporous 3D graphene-like carbons (OMGCs) constructed with tubular structures. OMGC synthesis can be realized by a dual templating method using mesoporous silica and in situ-generated molybdenum carbide as the exo- and endo-templates, respectively. The OMGCs simultaneously achieve a large surface area and high electrical conductivity. Benefitting from these advantages, Ru nanoparticles (NPs) supported on the OMGC show superior catalytic activity for alkaline hydrogen evolution reaction and anion-exchange-membrane water electrolyzer to Ru NPs on other OMCs and commercial Ru/C and Pt/C catalysts.
저자 백두산1, 이경아2, 김진영2, 주상훈1
소속 1울산과학기술원, 2한국과학기술(연)
키워드 촉매
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