화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-전기화학
제목 The critical role of residual lithium on surface of Ni-rich NCM cathode materials for all-solid-state batteries
초록 Typical NCM particle employedfor LIBs possess hierarchical morphology in which Li+ transferthrough crack is prohibited. Considering the different features of solidelectrolyte from a liquid electrolyte, here, we examined various cathodematerial design factors (particle size, morphology, and particle hardness) toachieve long-life cycle and good rate capability of ASBs. The crackinggenerated during electrode compression and the gradual particle structuredisintegration upon cycling are observed for LIB-grade NCM particle. Thismorphological failure was suspected as the main reason for a continuouscapacity fading. In the other hands, NCM particles in which particle hardnesswas conferred by tailored morphology design show improved cycling performances.The detailed results will be discussed at the meeting.
 
 
저자 강소라1, 김현승1, 정재엽1, 조우석1, 김영준2
소속 1한국전자기술(연), 2성균관대
키워드 All-solid-state battery; cathode; sulfide; residual lithium; interface
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