화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 가을 (10/24 ~ 10/26, 부산 BEXCO)
권호 18권 2호, p.1970
발표분야 에너지
제목 중온 고체산화물 연료전지를 위한 Bi2O3 doped SDC(Ce0.8Sm0.2O1.9) 전해질의 특성에 관한 연구
초록 Due to a good ionic conductivity, SDC(Samarium-doped ceria) can be used as an electrolyte of solid oxide fuel cells (SOFCs). However, to obtain the electrolyte with fully densification, SDC is required for high sintering temperature(1600℃).   
In this study, (25wt% and 30wt%) Bi2O3-doped SDCs are examined to lower densification temperature of SDC. Bi2O3-doped SDCs were sintered at 1000℃ and their porosities were measured by using ASTM method. (25wt% and 30wt%) Bi2O3-doped  SDCs show low porosity of 3% and 0.9% respectively, which is sufficient to use an electrolyte for SOFCs. The conductivity of Bi2O3-doped SDC pellet was also examined by 4-point probe method(At 800℃, (25wt% and 30wt%)Bi2O3-doped  SDC's conductivities were 0.3959 S/cm and 0.2535 S/cm, respectively).
Unlike 20wt% of the Bi2O3-doped SDC, (25wt% and 30wt%) Bi2O3-doped SDCs show single cubic phase and higher conductivity.  
저자 오창훈, 송신애, 김희수, 남석우, 윤성필, 한종희
소속 한국과학기술(연)
키워드 Bi2O3; SDC; fuel cell; Electrolyte
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