| 학회 | 한국공업화학회 |
| 학술대회 | 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 | 20권 2호 |
| 발표분야 | 촉매_포스터 |
| 제목 | Mesoporous ceria-metal composite catalysts for CO preferential oxidation reaction in excess H2 |
| 초록 | The preferential oxidation (PrOx) reaction is an efficient way to purity hydrogen produced by steam reforming of hydrocarbons and alcohols for application in proton exchange membrane fuel cell (PEMFC) for the removal of carbon monoxide, since the presence of CO impedes the H2/O2 reaction by the anode absorption of CO and the consequent poisoning. Optimum fuel cell efficiency requires complete removal of CO (＜ 10 ppm) from the hydrogen-rich gas feed. Catalysts reported for PrOx reactions are mainly precious metal catalysts, such as Au, Pt, Ru and Rh, exhibiting better low-temperature activity in comparison with base metal catalysts.However, as a noble metal-free alternative, the Cu-Ce-O system is a promising candidate, thanks to its low cost and high selectivity. In this work, a series of mesoporous mixed metal oxide catalysts prepared by nano-replication method was evaluated in the PrOx reaction. |
| 저자 | 이성빈, 이정화, 홍경희, 박진서, 김지만 |
| 소속 | 성균관대 |
| 키워드 | mesoporous material; preferential oxidation |
