| 학회 | 한국공업화학회 |
| 학술대회 | 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 | 19권 2호 |
| 발표분야 | 촉매_포스터 |
| 제목 | Promoted Rh nanocrystals encapsulated in ordered mesoporous complex material for higher alcohol synthesis |
| 초록 | Higher alcohols such as butanol are gaining attraction due to low water solubility, equivalent energy density to gasoline, low volatility, less corrosiveness, and so on. For the production of higher alcohols, highly ordered mesoporous material has been regarded as a good candidate for support since it has high surface area and uniform pore size distribution. In this study, promoted Rh catalysis were employed for higher alcohol synthesis. RMLF (Rh-Mn-Li-Fe) nanocrystals encapsulated in highly ordered silica-C and titania-C complex supports showed good catalytic performance in synthesis of ethanol, propanol and butanol, especially C3+ higher alcohols. The effluent gas from the reactor was analyzed by an online gas chromatograph (Young Lin Acme 6000 GC) employing a thermal conductivity detector and a flame ionization detector. N2 was used as an internal standard for GC analysis. |
| 저자 | 김태완1, 이진우2, 김성섭2, 하경수3, 임제미3, 김대각3, 오지환3 |
| 소속 | 1한국화학(연), 2포항공대, 3서강대 |
| 키워드 | Rh; Ordered mesoporous material; higher alcohol |
