| 학회 | 한국공업화학회 |
| 학술대회 | 2014년 봄 (04/30 ~ 05/02, 제주국제컨벤션센터) |
| 권호 | 18권 1호 |
| 발표분야 | 포스터-정밀화학 |
| 제목 | Deprotection study of N-protected azapropellanes |
| 초록 | Generally, polycyclic molecules with a highly symmetric structure such as cubane or isowurzitane have a higher molecular density as well as a molecular strain. In addition, molecules with higher nitrogen and oxygen atom contents tend to exhibit an increased detonation property as energetic materials. Combination of the polycyclic molecular skeleton and the higher N and O atom percentage would result in higher explosive performance as energetic materials as shown by octanitrocubane and HNIW. We have been recently involved in the synthesis of N-nitro substituted azapropellanes that can be used as novel starting materials for high energetic materials. Herein, we will present our effort for the deprotection of N-protected azapropellanes that have been reported very recently by our guoup.1 1. Young Gyu Kim et al. Tetrahedron, 2014, 70, 1617. |
| 저자 | 김명학1, 신문용1, 이병일1, 강재식1, 김진석2, 김영규1 |
| 소속 | 1서울대, 2국방과학(연) |
| 키워드 | deprotection study; azapropellanes; energetic materials |
