화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2005년 가을 (10/21 ~ 10/22, 인하대학교)
권호 11권 2호, p.2269
발표분야 에너지/환경
제목 Photocatalytic Methanol Reforming for Hydrogen Production
초록 The photocatalytic decomposition of aqueous methanol solution has been investigated using NiO/La2Ti2O7 and NiO/Sr2Nb2O7 photocatalysts. These are known as highly efficiency Layered perovskite photocatalysts which are active under UV light irradiation. There are optimum conditions for the hydrogen evolution, changing a molar ratio(H2O/methanol). Also hydrogen evolution rate can be enhanced by adding NaCl which is plentiful element in the seawater. Cocatalysts on the photocatalyst can improve the photocatalytic activities. We studied the effect of bimetal loading on the photocatalyst. Ni-Pt bimetal loaded photocatalyst shows higher activities comparing to single metal loaded photocatalysts. In order to investigate the decomposition mechanism of aqueous methanol solution, isotope analysis was performed using the quadrupole mass spectrometer.
저자 손효창, 장점석, 지상민, 배상원, 김현규, 이재성
소속 포항공과대
키워드 Photocatalysis; Methanol; Hydrogen
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