| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Naphtho[2,3-c][1,2,5]thiadiazole-based conjugated polymers |
| 초록 |
Donor-acceptor type copolymers employed naphtho[2,3-c][1,2,5]thiadiazole (NT) were synthesized to achieve low band gaps. As the same analogue of well-known PCZ-DTBT and PDTDPP-BT reported previously, carbazole (CZ) and dithiophene diketopyrrolopyrrole (DTDPP) units were selected as comonomers for photovoltaic and OFET applications, respectively. The resulting polymers, PCZ-DTNT and PDTDPP-NT with the molecular weight of 15,000 g/mol and 60,000 g/mol, exhibit the energy band gap of 1.74 eV and 1.24 eV, respectively. Preliminary photovoltaic performance of PCZ-DTNT shows the power conversion efficiency of 1.3% on conventional cells. PDTDPP-NT exhibits almost balanced ambipolar characteristics with the hole and electron mobility of 2.48 cm2 V-1s-1 and 2.04 cm2 V-1s-1 on FET devices. |
| 저자 |
김종기, 윤명희, 한아름, 이정훈, 김경식, 김보람, 김이호, 오준학, 김진영, 양창덕
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| 소속 |
울산과학기술대 |
| 키워드 |
naphtho[2; 3-c][1; 2; 5]thiadiazole; carbazole; dithiophene diketopyrrolopyrrole; low band gap; donor-acceptor type copolymer
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| E-Mail |
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