| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 가을 (10/09 ~ 10/10, 일산킨텍스) |
| 권호 |
33권 2호 |
| 발표분야 |
고분자 가공/복합재료 |
| 제목 |
Synthesis of SWNT Rings by Noncovalent Hybridization of Porphyrins and Single-Walled Carbon Nanotubes |
| 초록 |
Single-walled carbon nanotube (SWNT) rings have been synthesized via the noncovalent hybridization of carbon nanotubes and porphyrins. Optical absorption spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) results showed that the formation of the SWNT rings is strongly affected by the molecular architecture of the porphyrins, the hybrid concentration, the SWNT-to-porphyrin mass ratio, and the substrate on which the hybrid films were coated. We found that the SWNT hybrid rings result from the formation of porphyrin J-aggregates on the outer surfaces of the SWNTs and the tendency of porphyrins to aggregate in wheel structures. This novel method presents new theoretical challenges and potentially provides a simple approach based on the noncovalent hybridization of porphyrins and SWNTs to the synthesis of SWNT superstructures. |
| 저자 |
고영관1, 정희태2, 윤상천3, 김윤호3
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| 소속 |
1호남석유화학 대덕(연), 2KAIST 생명화학공학과, 3한국과학기술원 |
| 키워드 |
carbon nanotubes;
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| E-Mail |
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