화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 기능성 고분자
제목 Gas permeation characteristics of CNT-carbon molecular sieve composite membranes
초록 Carbon nano tubes (CNT)s were incorporated to enhance gas permeation and separation performance of carbon molecular sieves (CMS)s. CMS-CNT composites were prepared using direct mixing of CNT and poly (amic acid) precursors. Polyimide (PI)-CNT composites membranes were firstly obtained from these solutions by thermal imidization process. PI-CNTs were pyrolyzed up to desired temperature at an inert atmosphere to fabricate CMS-CNT composite membranes. The properties of the CMS-CNT composite membranes were characterized using X-ray diffraction, FT-IR, FE-SEM, mechanical tests, as well as thermal analysis. The gas permeability of CMS-CNT composites increased according to CNT contents with slight decrease of permselectivity. From this result, we can infer that the diffusional pathways for small gases were well created by the incorporation of CNTs.
저자 이재은1, 이영무1, 한상훈1, 정철호1, 박호범2
소속 1한양대, 2Department of Chemical Engineering
키워드 gas separation; CNT; polyimide
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