화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터)
권호 22권 2호, p.2135
발표분야 이동현상
제목 Mathematical Model of Energy Release due to Self-oxidation-reduction Reaction of Energetic Materials in Closed Chamber
초록 If we put energetic material made up of fuel and oxidizer in closed chamber and ignite, an oxygen atom which bonded with oxidizer obtain activation energy. Therefore, oxygen atom breaks the bonding with oxidizer and becomes free oxygen atom which can oxidize fuel. Heat generated from the reaction activates another oxygen atom. As a consequence, oxidation-reduction reaction is repeated until whole fuels are burned out. By the self-oxidation-reduction reaction, exothermic reaction which release heat, light and gas, etc. occurs and fuels rapidly burned. Because this phenomenon could be occurred under anaerobic conditions, it is applying to energy release of spacecraft and rocket needed to propel under anaerobic conditions. Due to growing interest in domestic aerospace industry, it is necessary to develop energy release model in order to apply to various research such as energy release performance evaluation and energetic material aging study, etc. This study makes mathematical model such energy release phenomenon of energetic material as pressure vs time equation. Additionally, pressure change according to time was also obtained and compared using various equations of state.
저자 공태연, 임도진
소속 부경대
키워드 열전달
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