화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 나노_포스터
제목 Preparation of Silicon Nanoball Encapsulated with Graphene Shell by CVD and Electroless Plating Process
초록 Carbon materials such as graphite have been widely used as the anode materials of secondary batteries. In spite of good stability, they are limited by low capacity. Silicon has a 4 times higher capacity than any other carbon material. It cannot be used, because it has  a low stability caused by the volume expansion. In this study, we fabricated a silicon nanoball encapsulated with graphene(Si-GB) to overcome the mentioned problems. In order to form a core/shell structured graphene encapsulated silicon nanoball, The Si-GBs were made by electroless plating method CVD process. The Si-GBs were formed with a spherical void between the silicon particle and the graphene layer, by which it has a better safety against to volumetric change of anode during lithiation/delitiation of repeated charging-discharging in secondary betteries. Morphology of the Si-GB was observed by the FESEM and the FETEM to find core-shell structured nanoball. The Si-GB was investigated by the Raman, the X-ray Photoelectron Spectroscopy to identify graphene layer on the surface of the inner silicon core.
저자 소대섭1, 박성진2, 허훈3, 김희진3
소속 1한국과학기술정보(연), 2인하대, 3한국생산기술(연)
키워드 graphene; silicon nanoball; encapsulate; CVD; secondaty battery
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