| 학회 | 한국화학공학회 |
| 학술대회 | 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔) |
| 권호 | 12권 1호, p.801 |
| 발표분야 | 열역학 |
| 제목 | Isothermal vapor-liquid equilibrium and excess molar volume for the binary mixtures of dibutyl ether(DBE) + ethanol, ethanol + benzene, and DBE + benzene |
| 초록 | Vast amounts of thermodynamic data needed for process modeling and the development of the parameters for thermodynamic models. However, the number of phase equilibria and mixing properties for the other ether compounds, such as ETBE, TAME, IPE and DBE, are much smaller than those of MTBE. In this work, isothermal vapor-liquid equilibrium(VLE) at 323.15 K for the binary sistems of dibutyl ether(DBE) + ethanol, ethanol + benzene, and DBE + benzene were measured with the help of headspace gas chromatography(HSGC). and excess molar volumes(VE) at 298.15 K for the same binary mixtures were determined from experimentally measured densities by using digital vibrating tube densimeter. The experimental VLE data were correlated with common gE model equations, and they were also compared with the predicted values by modified UNIFAC. The measured VE were compared with the correalted results by Redlich-Kister polynomial. All the measured data in this work showed good agreements with the calculated values. |
| 저자 | 오종혁1, 한규진2, 황인찬2, 박소진2 |
| 소속 | 1한국원자력(연), 2충남대 |
| 키워드 | VLE; excess volume; density; DBE; gasoline additive |
| 원문파일 | 초록 보기 |
