학회 | 한국화학공학회 |
학술대회 | 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔) |
권호 | 12권 1호, p.772 |
발표분야 | 열역학 |
제목 | Measurements and Correlation of High-Pressure VLE of Binary CO2+1,1,1,2-Tetrafluoroethane (HFC-134a) Systems |
초록 | Generally, vapor liquid equilibrium(VLE) data are required as one of the most important types of information in evaluating the performance of refrigeration cycles and determining their optimal compositions. A blend of Carbon dioxide and nonflammable HFC refrigerant may reduce both, global warming potential and flammability. In this work, the VLE data of binary mixture containing 1,1,1,2-Tetrafluoroethane and Carbone dioxide were measured at various isotherms (323.15 ~ 363.15 K). To facilitate easy equilibration, both the vapor and liquid phases were circulated separately in the experimental apparatus. The equilibrium composition for both vapor and liquid phases were analyzed by a gas chromatograph. The measure data were correlated with Wong-Sandler mixing rules and the Peng-Robinson equations of state[PR-EOS]. We compared the obtained data by using the PR-EOS with experimental data and reached a satisfactory consistency. |
저자 | 정연근, 임종성, 유기풍 |
소속 | 서강대 |
키워드 | VLE; R134a; CO2; 기액; 상평형; tetrafluoroethane |
원문파일 | 초록 보기 |