화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔)
권호 12권 1호, p.772
발표분야 열역학
제목 Measurements and Correlation of High-Pressure VLE of Binary CO2+1,1,1,2-Tetrafluoroethane (HFC-134a) Systems
초록 Generally, vapor liquid equilibrium(VLE) data are required as one of the most important types of information in evaluating the performance of refrigeration cycles and determining their optimal compositions. A blend of Carbon dioxide and nonflammable HFC refrigerant may reduce both, global warming potential and flammability.
In this work, the VLE data of binary mixture containing 1,1,1,2-Tetrafluoroethane and Carbone dioxide were measured at various isotherms (323.15 ~ 363.15 K). To facilitate easy equilibration, both the vapor and liquid phases were circulated separately in the experimental apparatus. The equilibrium composition for both vapor and liquid phases were analyzed by a gas chromatograph. The measure data were correlated with Wong-Sandler mixing rules and the Peng-Robinson equations of state[PR-EOS]. We compared the obtained data by using the PR-EOS with experimental data and reached a satisfactory consistency.
저자 정연근, 임종성, 유기풍
소속 서강대
키워드 VLE; R134a; CO2; 기액; 상평형; tetrafluoroethane
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