| 학회 | 한국고분자학회 |
| 학술대회 | 2003년 봄 (04/11 ~ 04/12, 연세대학교) |
| 권호 | 28권 1호, p.81 |
| 발표분야 | 고분자 가공/블렌드 |
| 제목 | The phase behavior of mixtures of two homopolymers with a block copolymer |
| 초록 | Phase behavior of mixtures consisting of polystyrene (PS) and poly(n-pentyl methacrylate) (PnPMA) with different amounts of PS-b-PnPMA are investigated measured by using turbidity and small angle light scattering. The PS/PnPMA blends without PS-b-PnPMA exhibited the combination UCST and LCST occurring at lower and higher temperatures. With increasing amounts of the block copolymer, the miscibility windows become wide, namely, UCST decreases whereas LCST increases. The increased miscibility was also elaborated by small angle neutron scattering measurements from which temperature dependence of the Flory-Huggins interaction parameter (χ) in homogeneous temperature regimes is known. This work was supported by National RND Program (M1-0214-00-0230) by MOST, by National Research Laboratory Program. |
| 저자 | 장진;류두열;김진곤 |
| 소속 | 포항공과대 |
| 키워드 | phase behavior |
