화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 고분자 구조 및 물성
제목 Electrical Reliability Study of Nanoporous Organosilicate Dielectrics
초록 The next generation semiconductors call for ultra-low dielectric materials to reduce the RC delay and cross-talk caused by the extremely small circuit dimension. In order to decrease the dielectric constant, we introduced the porogen into dielectric material. Ultra-low dielectrics (k < 2.3) with desirable pore morphologies and high mechanical strength were prepared using a β-cyclodextrin based reactive porogen and the copolymer of methyl trimethoxysilane with 25 mol% of bis-1,2-triethoxysilyl ethane was used as an organosilicate matrix. We examined electrical reliability using VRDB (voltage ramping dielectric breakdown) test with the same matrix but with different porosity. We made a comparative study of dielectric breakdown at Cu and Ta electrode, and on 100 Å and 1000 Å SiO2. VRBD of each dielectric material with different porosity was measured, and we found that the VRBD of Ta electrode system is a little higher than that of Cu electrode system because of the Cu migration.
저자 이용준1, 박건우1, 최현상1, 윤도영2, 주영창2, 이희우1
소속 1서강대, 2서울대
키워드 porogen; Reliability; cyclodextrin; dielectric
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