| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
대학원생 구두발표 |
| 제목 |
The Influence of Hydrogen Bonding in Block Copolymer Transition |
| 초록 |
It is well known that the block copolymer (BCP) forms a complex with low molecular weight molecules as well as with macromolecules, which has applications in various fields. We investigated transition behavior for block copolymer mixtures composed of a symmetric polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) and phenylacetamide derivatives, where the hydroxyl functionality at para postion is available only for 4-hydroxyphenylacetamide (HPA) and not for phenylacetamide (PA). In comparison to PA, the increase in TODT with the addition of HPA was observed and measured by in-situ small angle x-ray scattering (SAXS) and depolarized light scattering (DPLS), and an annealing temperature dependence for BCP mixtures with HPA indicates that only the complex by H-bonding mediation between the nitrogen units of P2VP block and hydroxyl group in the HPA enhances nonfavorable segmental interactions between two block components. |
| 저자 |
나이두1, 안형주1, 이호연1, 정영미2, 류두열1
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| 소속 |
1연세대, 2부산대 |
| 키워드 |
block copolymer; transition; H-bonding; supramolecules
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| E-Mail |
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