| 학회 |
한국화학공학회 |
| 학술대회 |
2010년 봄 (04/22 ~ 04/23, 대구 EXCO) |
| 권호 |
16권 1호, p.37 |
| 발표분야 |
고분자 |
| 제목 |
Synthesis and characterization of branched and fluorinated poly(arylene ether sulfone) electrolyte membranes for fuel cell applications |
| 초록 |
This report describes the preparation and characterization of branched and sulfonated poly(arylene ether sulfone) copolymer (PAES) membranes containing perfluorocyclobtane moieties. Two different monomers, 4,4'-bis(trifluorovinyloxy)biphenyl, 4,4'-sulfonyl-bis(trifluorovinyloxy)biphenyl and a brancher 1,1,1-tris(4'-trifluorovinyloxyphenyl)ethane were synthesized through fluoroalkylation and Zn-mediated dehalogenation. They were then terpolymerized through thermal [2π+2π] cycloaddition. The branching degree of the terpolymers were controlled by the brancher content. Lastly they were post-sulfonated with chlorosulfonic acid. Their properties such as water uptake, ion exchange capacity and ion conductivity were observed in terms of sulfonation degree and branching degree. |
| 저자 |
전성훈1, 박재완2, 장봉준3, 김정훈1, 주혁종4
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| 소속 |
1Environment & Energy Research Center, 2Korea Research Institute of Chemical Technology / Department of Polymer Engineering, 3Chungnam National Univ., 4Korea Research Institute of Chemical Technology |
| 키워드 |
branched polyelectrolyte; fluorinated polymer; proton exchange membrane; poly(arylene ether sulfone); fuel cell
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| E-Mail |
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| 원문파일 |
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