| 학회 |
한국공업화학회 |
| 학술대회 |
2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
26권 1호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Olefinic block copolymer (OBC)/trans-polyoctenamer (TOR) blends with shape memory effect |
| 초록 |
Shape memory polymer blends were prepared by melt blending of a thermoplastic elastomeric olefinic block copolymer (OBC) and semicrystalline trans-polyoctenamer (TOR). Phase morphology studies and differential scanning calorimetry analysis showed that the blends form immiscible phase-separated structure. Dynamic mechanical analysis of the blends showed a sudden drop in the storage modulus at melting temperature of TOR phase followed by a plateau region till the melting of OBC phase occurs. Such structural features of the blends render them to exhibit thermally triggered shape memory behavior, where OBC contributed to shape recovery and TOR served as a switch polymer in the blend. Effects of blend composition on shape memory behavior (shape fixity and shape recovery) and mechanical properties were investigated. |
| 저자 |
안혁준, 김강우, 장영욱
|
| 소속 |
한양대 |
| 키워드 |
olefinic block copolymer; trans-polyoctenamer; thermal activated shape memory effect
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| E-Mail |
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