| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO)) |
| 권호 |
22권 1호 |
| 발표분야 |
디스플레이_포스터 |
| 제목 |
Synthesis, Characterization, and Device Fabrication of Homoleptic Phenylimidazolinato Ir(III) Complexes Geometrically Confined with Bulky m-Terphenyl Group |
| 초록 |
Series of six terphenyl-modified phenylimidazolinato Ir(III) complexes with various substituents at 4-position of phenyl ring and 5-position of terphenyl ring were prepared. We have come up with the idea of implementing sterically bulky ligand that can help the metal-centered triplet state unstable; this brings us to use the terphenyl ligands. It was found that the bulkiness control of substituent on imidazole ring plays an important role in emission behavior of Ir-complexes. We performed theoretical quantum chemical calculations and measured experimental temperature dependent emission lifetime to explain the importance of bulky substitution in designing blue emissive Ir(III)-complex. Implications of the present observations and mechanism are discussed in detail. |
| 저자 |
곽수진, 김소연, 김진형, 이승준, 김철훈, 강상욱, 손호진
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| 소속 |
고려대 |
| 키워드 |
Ir complex |
| E-Mail |
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