화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2017년 봄 (04/26 ~ 04/28, ICC 제주)
권호 23권 1호, p.112
발표분야 고분자
제목 Uniaxial Alignment of 1D Nanomaterials via Photo-induced Directional Mass Migration of Azopolymer Nanocomposite Microparticles
초록 Photo-responsive property of azopolymers has attracted significant research interest for their broad range of potential applications. Upon exposure to light, azo polymers undergo reversible trans-cis isomerization, which results in directional mass transport in the polymer matrix (“athermal photofluidization”). Based on this phenomenon, in this study, we aimed to explore new possibility of azopolymers as a universal director of 1-dimensional (1D) nanomaterials. Azopolymer nanocomposite microparticles containing ZnO nanowires (NWs) were synthesized by microfluidic system. To induce directional photofluidization of azopolymer, linearly polarized laser beam (467nm) was irradiated to the particles. With anisotropic deformation of microparticles, the encapsulated NWs were successfully aligned along the direction of polarized light owing to the internal mass migration of azopolymer.
저자 정유진, 유필진
소속 성균관대
키워드 기능성고분자; 고분자복합재료
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