학회 |
한국고분자학회 |
학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
권호 |
40권 2호 |
발표분야 |
대학원생 구두발표 (영어발표, 발표15분) |
제목 |
Stimuli-responsive Polymer Brushes on Graphene Oxide for Controlled Plasmonic Coupling of Gold Nanorods |
초록 |
Stimuli-responsive polymer brushes on a variety of substrates and graphene oxide-based nanomaterials have been widely investigated for developing advanced biosensors. In this study, stimuli-responsive polymer brushes on two dimensional nanoscale graphene oxides (NGOs) were prepared to control plasmonic coupling of gold nanorods (GNRs). Negatively charged poly(N-isopropylacrylamide-co-acrylic acid), poly(NIPAAM-co-AAc) brushes with stimuli-responsiveness were grown on the NGOs via surface initiated atom-transfer radical polymerization, followed by complexation of positively charged GNRs with the poly(NIPAAM-co-AAc) brushes on the NGOs. The poly(NIPAAM-co-AAc) brushes on the NGOs were collapsed above low critical solution temperature, resulting in increased plasmonic coupling of GNRs. Conclusively, the GNRs-incorporated poly(NIPAAM-co-AAc) brushes on the NGOs would serve as nanoprobes for photonics-based biosensing. |
저자 |
임동우1, Ahmed Ali2
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소속 |
1Department of Bionano Engineering & Department of Bionanotechnology, 2Hanyang Univ. |
키워드 |
Stimuli-responsiveness; Polymer brushes; Graphene oxide; Gold nanorods; Plasmonic coupling
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E-Mail |
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