| 학회 | 한국공업화학회 |
| 학술대회 | 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 | 19권 2호 |
| 발표분야 | 정밀화학_포스터 |
| 제목 | N-functionalization of pentaazapropellane |
| 초록 | Explosive performances of energetic materials are influenced by their molecular structure, heats of formation, and the N/O/C balance in the molecules. Hexanitrohexaazaisowurtzitane (HNIW) is one of the most powerful high explosives in commercially available known to date. Azapropellanes with a high N/O content are rather strained but easier to synthesize. Some nitroazapropellanes with the N-NO2 groups have been calculated to release higher detonation power than well-known RDX or HMX. We have recently published the synthesis of several novel pentaaza[3.3.3]propellanes and their N-nitro derivatives. In this presentation, we will report the N-functionalization study of some pentaaza[3.3.3]propellanes and their characterization results. |
| 저자 | 김영규1, 김진석2, 오정환1, 김남태1, 이병일1 |
| 소속 | 1서울대, 2국방과학(연) |
| 키워드 | high energy materials; azapropellane; protection; nitration |
