화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2008년 봄 (05/09 ~ 05/10, 한양대학교(안산))
권호 12권 1호
발표분야 고분자
제목 Synthesis and Surface Properties of Superhydrophobic Polyurethane
초록 Novel fluorinated polyurethane elastomers were synthesized by two step urethane reaction of the fluorinated polyols based on poly(vinylidenefluoride-co-hexafluoro perpene)(2,000g/mol) or Fomblin ZDOL®(2,000g/mol) and diisocyanate such as 4,4'-methylene-bis(phenyl isocyanate)(MDI) in the presence of a solvent (DMAc/THF;3/1), followed by subsequent chain extension with 1,4-butanediol. In order to control the fluorinated polyol moiety of the soft segment in the synthesized elastomer to 10~50mol%, polyether type polyols such as polytetramethylene glycol(PTMG; 2,000g/mol)) were mixed during the polymerization reaction. The structure and surface properties of polyurethane containing fluoropolyols were confirmed by using FT-IR, XPS and Water Contact Angle meter.
저자 이종섭, 김두환, 신범식, 정권영, 김태중, 이범재
소속 충남대
키워드 Surperhydrophobic polyurethane; Fluoropolyol; Surface properties
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