화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 환경에너지
제목 Fluorination effect of activated carbons as electrode materials on asymmetric capacitive deionization
초록 Activated carbons (ACs) have been fluorinated and prepared to electrode to identify desalination performance according to the sign of fluorinated AC electrode (ACF) using asymmetric capacitive deionization (CDI) cells. Changes in pore structure and surface functional groups of ACs after fluorination were measured using an ASAP 2020 and X-ray photoelectron spectroscope (XPS), respectively. The desalination performance of asymmetric CDI cells assembled with an untreated AC electrode (ACR) as the counter electrode and an ACF as the cathode (R/F-) or anode (R/F+) was studied at 1 V. For R/F-, the salt adsorption capacity and charge efficiency increased from 10.1 mg/g and 0.56 to 12.5 mg/g and 0.73, respectively, compared with the CDI cell assembled with identical R-AC electrodes. It is attributed that ACF has a cation attractive effect originating from the partially negatively charged fluorine functional groups on the AC surface.
저자 조한주, 김경훈, 정민정, 이경민, 이상민, 이영석
소속 충남대
키워드 fluorination; activated carbons; asymmetric capacitive deionization
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