화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 41권 1호
발표분야 분자전자 부문위원회 I
제목 Low-Band gap Polymer-Based Ambipolar Transistors and Inverters Fabricated Using a Flow-coating Method
초록 The slow evaporation of a high boiling point(bp) solvent permitted sufficient time for the semiconducting polymer chains to self-organize during the process, thereby improving the film crystallinity and inducing favorable polymer chain orientations for charge transport. We demonstrated the formation of highly crystalline polymer films using a flow-coating method to enable the fabrication of ambipolar transistors and inverters. Importantly, unlike conventional spin-coating methods, the flow-coating method allowed us to use high bp solvents, even on a hydrophobic surface, and minimized the polymer solution waste. The crystalline orientations of the polymers could be tuned depending on the solvent used and the employment of a thermal annealing step. The use of high bp solvents and thermal annealing of the polymer films enhanced the crystalline microstructures in the flow-coated films to increase the carrier mobility in the OTFTs by an order of magnitude compared to the spin-coated films.
저자 김민제1, 박재훈1, 강보석2, 정아라3, 양지혜4, 강문성4, 이동윤5, 조길원2, 김봉수3, 조정호1
소속 1성균관대, 2포항공과대, 3이화여자대, 4숭실대, 5경북대
키워드 Organic field-effect transistorm; high carrier mobility; different solvent; film crystallinity
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