| 학회 |
한국공업화학회 |
| 학술대회 |
2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
26권 1호 |
| 발표분야 |
포스터-환경·에너지 |
| 제목 |
chitosan-Ag(I) facilitated transport membranes for CO/N2 separation by reversible π-complexation |
| 초록 |
Carbon monoxide (CO) is an important raw material in chemical industries. In steel industry, A huge amount of CO has been produced as a byproduct (LDG, BFG) containing N2, CO2, CH4, H2 etc. To recover CO from other gases, CO/N2 separation is very important because CO and N2 have similar kinetic diameters and solubility. In this work, a chitosan-based composite membrane containing Ag ions was prepared for the selective separation of CO from N2 via the facilitated transport mechanism. Chitosan membrane containing Ag ions showed excellent CO permeability (P=>22~35.8 GPU) and high CO/N2 selectivity (α=>29.2~37.2). CO separation experiments were performed from CO/N2 mixture gases with various CO compositions (50, 60, 80, 95 mol %). Long-term operation test using mixed gases was performed and showed the long-term stability(~100 h) with >97% CO purity, which confirms the facilitated membranes developed could be used commercially. |
| 저자 |
민수빈1, 서채희1, 안이삭1, 임시우1, 최기환1, 박보령1, 김종학2, 김정훈1
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| 소속 |
1한국화학(연), 2연세대 |
| 키워드 |
CO separation; facilitated transport membrane; chitosan membrane
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| E-Mail |
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