| 학회 |
한국고분자학회 |
| 학술대회 |
2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO)) |
| 권호 |
45권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Efficient Conduction of Nonconjugated Small-Molecule Organic Radicals |
| 초록 |
We present a molecular conductor towards a novel class of electronic material. We investigate electrical properties of a stable radical, h-TEMPO ( 4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl), which has well been known for containing stable radicals. The chemical component of this radical molecule allows us to form a single crystal via physical vapor deposition (PVD). The charge transport of this macroscopic open-shell single crystal is rather low, but the thermal annealing of a well-defined single crystal allows the molecule to have a fast charge transfer reaction due to the electronic communication of the open shell site with each other, which results in electrical conductivities greater than 0.05 S m–1. This effort shows a model that differs significantly from the conjugated polymers or molecules generally accepted for the generation of next generation conductors. |
| 저자 |
조예린1, 유일환1, 고재형1, 김대윤1, 손대원2, 주용호1
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| 소속 |
1한국과학기술(연), 2한양대 |
| 키워드 |
radical; conduction
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| E-Mail |
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