| 초록 |
A new organic photovoltaic polymer, a tetrathiafulvalene (TTF)-based main-chain polymer and contained fullerene (C60), was successfully synthesized via a condensation polymerization. TTF can work as an electron donor (D) and C60 can act as an electron acceptor (A). Therefore, the chemical component of TTF-DA-polymer is a DA dyads system. The chemical structure of TTF-DA-polymer was characterized by spectroscopic techniques such as FT IR, 1H and 13C NMR spectroscopes, and its thermal transition behavior was also monitored by DSC. Moreover, the electrochemical properties and photoelectric properties were researched by cyclic voltammetry, photoluminescence, and ultraviolet-visible spectrometer. This work was supported by a grant from the Korea Institute of Science and Technology (KIST) Institutional Program (2Z04320), Basic Science Research Program (2013R1A1A2007238), SW Fusion Components R&D Program (MOTIE-10047806) and BK21Plus Program, Korea. |
