| 초록 |
This presentation describes the synthesis of functional, fibrous polymer monoliths with hierarchical structure. The monoliths were designed on the basis of conjugated microporous polymer (CMP)-based fiber networks and facilely synthesized via a bottom-up approach. The nitrogen atoms doped on the skeletal backbone resulted in the uniform growth of zeolite imidazolate framework (ZIF) nanocrystals on the surface of the fiber structure, and the nanocrystals promoted the thiol-epoxy reaction to induce further encapsulation of the fiber strands of the monoliths. In particular, during the reaction, we were able to create molecularly imprinted sites on outer layers of the fibrous monoliths, which then caused effective molecular binding toward diethylstilbestrol, an endocrine disruptor. |
