화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 기능성 고분자
제목 Fabrication of mesoporous silica nanofibers by dual-surfactant system and their application to catalyst
초록 Mesoporous silica Nanofibers (MSNFs) were fabricated by dual-surfactant system in the nanopores of anodic alumina oxide (AAO). Vapor deposition synthesis was used to introduce the silica precursor in the nanopore of AAO. The mesoporous structure of the MSNFs could be controlled by concentrations of pluronic and cationic surfactants in dual-surfactant system, operation temperature, and concentration of HCl for condensation. Furthermore, heterogeneous catalysts were prepared by attaching an amino silane on the surface of mesopores of MSNFs. MSNFs with amino group functionalized cylindrical mesopores exhibited over 90% of conversion yield, near 100% of selectivity.
저자 오현택, 민사훈, 이경진, 장정식
소속 서울대
키워드 mesoporous silica; AAO; vapor deposition synthesis; heterogeneous catalyst
E-Mail