화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2006년 봄 (05/12 ~ 05/13, 전북대학교)
권호 10권 1호
발표분야 고분자
제목 Synthesis of Novel Amphiphilic Diblock Copolymers Containing Polyhedral Oligomeric Silsesquioxane (POSS) Using Ring Opening Metathesis Copolymerization
초록 Living ring opening metathesis copolymerization of the polyhedral oligomeric silsesquioxane (POSS) monomer (NBEPOSS) and 5-norbornene-2,3-dicarboxylic acid bis trimethylsilyl ester(NBETMS) was performed with Grubbs' catalyst, RuCl2(=CHPh)(PCy3)2. The block copolymers were then converted to diblock copolymers with 5-norbornene-2,3-dicarboxylic acid (NBECOOH) and NBEPOSS two blocks by precipitating the polymer solutions in a mixture of methanol, acetic acid, and water.
저자 권영환, Wentao Xu
소속 대구대
키워드 ROMP; POSS; Block copolymer
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