학회 | 한국공업화학회 |
학술대회 | 2006년 봄 (05/12 ~ 05/13, 전북대학교) |
권호 | 10권 1호 |
발표분야 | 고분자 |
제목 | Synthesis of Novel Amphiphilic Diblock Copolymers Containing Polyhedral Oligomeric Silsesquioxane (POSS) Using Ring Opening Metathesis Copolymerization |
초록 | Living ring opening metathesis copolymerization of the polyhedral oligomeric silsesquioxane (POSS) monomer (NBEPOSS) and 5-norbornene-2,3-dicarboxylic acid bis trimethylsilyl ester(NBETMS) was performed with Grubbs' catalyst, RuCl2(=CHPh)(PCy3)2. The block copolymers were then converted to diblock copolymers with 5-norbornene-2,3-dicarboxylic acid (NBECOOH) and NBEPOSS two blocks by precipitating the polymer solutions in a mixture of methanol, acetic acid, and water. |
저자 | 권영환, Wentao Xu |
소속 | 대구대 |
키워드 | ROMP; POSS; Block copolymer |