학회 | 한국화학공학회 |
학술대회 | 2015년 가을 (10/21 ~ 10/23, 일산 KINTEX) |
권호 | 21권 2호, p.2193 |
발표분야 | 촉매 및 반응공학 |
제목 | Steam-CO2-Reforming of methane over MgO-MgAl2O4 structural catalyst with controlled pore morphologies |
초록 | Magnesium oxide (MgO) as a support for a nickel catalyst has been much attracted because it has excellent capability to inhibit the carbon coking during the Steam-CO2-Reforming (SCR) of methane. In spite of the benefit, the application of MgO as the catalyst support has been limited in the SCR of methane because of its low mechanical strength. Magnesium aluminate spinel (MgAl2O4) offers a desirable combination of properties for use in the catalyst, due to its high melting temperature, good chemical stability and mechanical strength. The intrinsic factors of the catalyst support affecting the SCR reaction are the pore size, pore shape, pore surface area, and so on. In this study, we controlled the factors artificially by changing the shape of MgO precursors such as cube-like and sphere-like shape in the MgO-MgAl2O4 structural catalyst support. And we compared the effects of Ni/MgO-MgAl2O4 structural catalysts including different shape of MgO precursors on the SCR reaction. |
저자 | 김상우1, 이관영2, 문동주1, 안병성1, 임상진3 |
소속 | 1KIST, 2고려대, 3KIST / 고려대 |
키워드 | Magnesium Oxide; MgAl2O4; SCR; Structural catalyst support; Particle shape; Pore surface; Pore size; Pore shape |
원문파일 | 초록 보기 |