화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터)
권호 43권 1호
발표분야 고분자합성
제목 Palladium supported on porous polyurea frame works : An efficient heterogeneous catalyst for Suzuki-Miyaura cross-coupling reaction.
초록 The palladium-catalyzed Suzuki-Miyaura coupling reaction is one of the most important organic transformations for the construction of carbon-carbon bonds. Its widespread use in the synthesis of natural products, pharmaceuticals, agrochemicals, and polymers is a testament to its broad impact on the chemical science. In this aspect, Porous organic polymers (POPs) are noticeable materials because of their special properties such as physical stability, permanent surface porosity, large surface area, and frameworks with tunable functional groups. Especially, POPs received much attention as heterogeneous catalysts because of their ability to control functional group and ligand by chemical reaction. In this study, POP synthesized by urea reaction because the urea functional group has many sites that can immobilize palladium. The experimental was characterized by FT-IR, XPS, BET, SEM, GC
저자 소재일, 천영걸, 류지형, 심상은
소속 인하대
키워드 urea; porous organic polymer; heterogeneous catalyst
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