화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 기능성 고분자
제목 Two-Dimensional Large-Area Graphitic Structure Driven from Hyperbranched Polymer
초록 Graphene, two-dimensional (2D) single layer of carbon atoms, is a promising material having remarkable properties such as zero-band gab, ambipolar electric field effect, quantum Hall effect and so on. Currently, many researches focus on obtaining low-cost and high-quality graphene via chemical vapor deposition (CVD), oxidation of graphite, electrochemical exfoliation of graphite and so on. Here, we report a new method for the formation of large-area graphitic film from hyperbranched polymer, which is prepared from the polymerization of 4-ethylbenzoic acid (EBA). The resultant hyperbranched polymer displayed 2D crystalline structure As a result, 2D graphitic structure, which was observed by transmission electron microscope (TEM) and atomic force microscopy (AFM), could be formed by a simple solution casting and subsequent thermal annealing.
저자 배서윤, 백종범
소속 UNIST
키워드 Graphene; Graphite; Hyperbranched polymer; crystal structure
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