화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 봄 (04/25 ~ 04/27, 제주 ICC)
권호 18권 1호, p.383
발표분야 분리기술
제목 Pd alloy composite membrane deposite on a porous nickel support modified with diffusion barrier by sputtering method
초록 In this study, ceramic barrier was introduced on the surface of a porous nickel support (PNS) to prevent intermetallic diffusion. The ZrO2 was sputtered on the PNS by RF sputtering to be 200 nm. Pd and Au were deposited by DC and RF sputtering on the ZrO2 modified PNS with thicknesses of 4 μm and 0.5 μm, respectively. The permeation measurement was carried out using hydrogen and helium at 400 oC and a pressure difference of 100-2000 kPa. The gas permeation tests confirmed that the hydrogen permeation flux increased with increasing pressure difference to 3.33 mol m-2 s-1 at 2000 kPa with H2/He selectivity of 5600.
저자 이춘부1, 이성욱1, 박진우1, 이신근1, 최승훈2, 김성현3, 박종수1
소속 1한국에너지기술(연), 2서남대, 3고려대
키워드 H2; Pd membrane; separation; sputtering deposition; diffusion barrier
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