화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 47권 1호
발표분야 고분자가공/복합재료/재활용
제목 Effect of Functional Heterocyclic Surfactant on the Mechanical Properties of Biodegradable and Sustainable Bio-Nanocomposite
초록 A biodegradable and sustainable polymer nanocomposite (BSPN) is prepared and its mechanical properties are examined in this study. Conjugating isosorbide and isophorone diisocyanate results in the formation of a functional heterocyclic surfactant (HCS). BSPN is then produced by thermally blending HCS with poly(butylene adipate terephthalate) (PBAT) and cellulose nanofiber (CNF). While CNFs are intrinsically highly aggregated with each other due to strong hydrogen bonds between them, HCS induces effective exfoliation of aggregated CNFs and also CNF dispersion in the PBAT matrix during the thermal blending process. BSPN exhibits superior mechanical properties to pure PBAT, which is due to the unique interaction between PBAT and well-dispersed CNFs. The mechanism for enhanced mechanical properties of BSPN is also proposed using FT-IR spectroscopy.
저자 최기원1, 권하늬2, 홍평화2, 고민재1, 홍성우2
소속 1한양대, 2한국생산기술(연)
키워드 Biodegradable; Sustainable; Toughness; Heterocyclic Surfactant; PBAT; CNF
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