| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터) |
| 권호 |
40권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Ion sensitive Polypepetide Block Copolymer |
| 초록 |
Poly(L-alanine)/poly(L-glutamic acid/DL, D, and L-alanine) /poly(ethylene glycol)/poly(L-glutamic acid/DL, D, and L-alanine)/poly(L-alanine) (〔PA-PEA-PEG-PEA-PA〕) multiblock copolymers were synthesized as an ion sensitive polypeptide polymer. The dissociation constants between the metal ions and the multiblock copolymers were calculated by UV-Visible spectrometer using murexide dye. Size and secondary structure of the multiblock copolymers containing metal ions were also measured by dynamic light scattering and circular dichroism spectroscopy, respectively. The above results suggested that metal ions and the multiblock copolymers forms strong ionic complexes even in a millimolar range of the metal ion concentration. |
| 저자 |
정희정1, 이선숙2, 김혜안2, 문효정2, 남상아2, 정병문2
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| 소속 |
1이화여대, 2이화여자대 |
| 키워드 |
ion sensitive; calcium; peg; copolymer
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| E-Mail |
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