화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2006년 봄 (05/12 ~ 05/13, 전북대학교)
권호 10권 1호
발표분야 정밀화학
제목 Efficient and Selective Synthesis of 2,6-Dimethylnaphthalene (2,6-DMN)
초록 2,6-Dimethylnaphthalene (2,6-DMN) is an important raw material for the synthesis of polyethylene naphthalate (PEN) which is used as special films, fibers and new engineering plastics. 2,6-DMN was selectively synthesized in overall 64% yield over two steps. 2,6-DMN was prepared by catalytic Friedel-Crafts intramolecular cyclization of the γ-aryl aldehyde resulted from a ligand-free Heck reaction.

저자 임태은, 김병현, 이종길, 김영규
소속 서울대
키워드 2; 6-Dimethlynaphthalene; 2; 6-DMN; PEN; Heck reaction; aromatic electrophilic cyclodehydration
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