| 학회 | 한국고분자학회 |
| 학술대회 | 2003년 가을 (10/10 ~ 10/11, 부경대학교) |
| 권호 | 28권 2호, p.289 |
| 발표분야 | 특별 심포지엄 |
| 제목 | Novel Ruthenium catalyst for ring opening metathesis polymerization |
| 초록 | Ring opening metathesis polymerization (ROMP) is one of the important polymerization methods since it has living polymerization nature and is a useful technique to get a copolymer of a various norbornenes. The catalyst for ROMP is transition metal carbene complex and is very sensitive to the moisture. over the past decade, Grubb's group and other researchers have devoted to search a more stable and more active catalyst for metathesis, since it posses significant advantage in terms of handling. Up to now, Grubb's (2) is one of the most stable and reactive catalyst for ROMP. In this work, we have synthesized novel catalyst by modification of the Grubb's catalyst to enhance environmental stablity. They showed the good catalytic activity without degasification and purification of solvent even with very small amount of catalyst for ROMP of norbornene. |
| 저자 | 권경아, 엄민식, 진문영, 전기원, 이철위, 김미옥 |
| 소속 | 한국화학(연) |
| 키워드 | ROMP; ruthenium |
