| 학회 |
한국화학공학회 |
| 학술대회 |
2018년 가을 (10/24 ~ 10/26, 대구 EXCO) |
| 권호 |
24권 2호, p.2140 |
| 발표분야 |
[C1가스리파이너리사업단 국제 심포지엄] 화학촉매 관련(촉매부문위원회) |
| 제목 |
Unprecedented catalytic activity as a result of direct heterogenization of a homogeneous catalyst for epoxide carbonylation |
| 초록 |
The synthesis of a unique heterogeneous catalyst that combines the functionality of a homogeneous catalyst and the advantages of a heterogeneous catalytic process is a continuing goal in catalysis for the various reaction which applicable in industries. The recent results on direct heterogenization of homogeneous catalyst for lactone production from epoxide carbonylation through a facile polymerization using Friedel-Crafts alkylation will be presented. The synthesized single-site heterogeneous catalysts are produced b-butyrolactone with a remarkable turnover frequency (TOF) of 400 h-1,and recycled experiments of this catalyst demonstrate it as a possible candidature for industrial applications. |
| 저자 |
윤성호, Rajendiran Senkuttuvan
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| 소속 |
국민대 |
| 키워드 |
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| E-Mail |
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| 원문파일 |
초록 보기 |
