| 초록 |
An emerging class of excellent explosives is coordination polymers (CPs), which exhibit both stability and tunability originated from the components, metal and organic building units. Explosive properties of CPs are demanded by the organic building units. Among the energetic organic building units, 1H,1H’-[5,5’-bistetrazole]-1,1’-diol (H2BTO) is attracted interest due to the high-energetic performing tetrazole ring and good thermal stability attributed to N-oxide. Herein, we report the new 1D metal-organic nanoribbons (MONs) with BTO linker, together with Cu and Mn metals. These straight-type of MON-1 ([Cu(BTO)(DMA)2]) and helical-type of MON-2 ([Mn(BTO)(DMA)2]), where DMA (N,N-Dimethylacetamide), have excellent explosive properties. |
