화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 고분자구조 및 물성
제목 Electrochromic properties of viologen polymers based on bipyridyl and various benzidine derivatives
초록 In this experiment, the electrochromic material was synthesized using bipyridyl to synthesize high molecular viologen according to the characteristics of various positions and functional groups, and the electrochromic characteristics were compared using this. The synthesized polymer was analyzed by FT-NMR and FT-IR. Through this, the electrolyte was manufactured and a sandwich-type cell was manufactured and various electrochromic characteristics were measured. As a result, it was confirmed that the material substituted at the ortho site of benzidine showed lower electrochromic characteristics such as discoloration efficiency and stability than the material substituted at the meta site. It was confirmed that all polymers except for -CF3 substituted at the ortho site showed more than 100㎠/C, and the group that pushed electrons at the meta site maintained a high transmittance difference for a long time.
저자 신해인, 이승우, 여지현
소속 영남대
키워드 viologen; electrochormic; bipyridyl
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