| 학회 | 한국공업화학회 |
| 학술대회 | 2014년 봄 (04/30 ~ 05/02, 제주국제컨벤션센터) |
| 권호 | 18권 1호 |
| 발표분야 | 기능성 다공 무기소재 |
| 제목 | Structure of Nanoporous Materials and Their Physical or Chemical Properties |
| 초록 | In this talk, two nanoporous materials - a zeotype material, ETS-10 and a metal-organic framework material, CDMOF-2 - in particular, the relationship between their structures and physicochemical properties will be presented. In a representative zeotype material, ETS-10 crystal, the TiO32- quantum wires (QWs) are running along the [110] and [1-10] directions, respectively. Due to a large number of inherent defects, the TiO32- QWs with varying lengths and local densities are expected. However, there have been no methods to analyze the distribution pattern of their relative lengths, length homogeneities, and local densities within a crystal. In this talk, how to analyze the distribution pattern of the wires in a big ETS-10 crystal will be discussed. A metal-organic framework (MOF), CDMOF-2 contains γ-cyclodextrins (γ-CDs) and Rb+ linker. It features reversible chemical binding of CO2 to primary hydroxyl groups on γ-CD. As a broad, fundamental investigation, we observed high ionic conductivity, relatively, with the “as synthesized” version of CDMOF-2 following sorption of methanol as a pore filling solvent. |
| 저자 | 정낙천 |
| 소속 | 대구경북과학기술원 |
| 키워드 | zeolite; MOF |
